Volume 1 built the foundation. Volume 2 is where the Code gets specific.
Once you can read the general rules, the real work starts: hazardous locations, special occupancies, special equipment and special conditions.
Michael Hayes' Guide to Comprehending the National Electrical Code Vol. 2 picks up exactly where Volume 1 stops, at Article 500, with the same plain-English approach: what the requirement says, why it exists, and how it looks in the field.